电化学2005，Vol.11Issue(4)：360-368,9.
自掺杂磺酸化聚苯胺之最优化实验设计
The Optimal Sulfonation Conditions of Self-doped Polyaniline Obtained by Using Experimental Strategies
摘要
Abstract
The optimal sulfonation condition of self-doped sulfonated polyaniline ( prepared from leucoemeraldine base; denoted as LEB-SPANI) with a high electronic conductivity was obtained by experimental strategies, including the fractional factorial design (FFD) and central composite design (CCD). From the FFD experiment, the selfdoped LEB-SPANI prepared at a low temperature (4℃), a short reaction time ( 1 h), and a small volume of fuming sulfuric acid ( 10 mL) showed a better conductivity (ca. 127 mS/cm). In the CCD study coupled with a confirmation test, the highest conductivity (ca. 141 mS/cm) of the LER-SPANI film was obtained under a sulfonation temperature of 4℃, a sulfonation time of 75 minutes, and a volume of 8 mL of 30% fuming sulfuric acid. The textural cha-racteristics of self-doped LEB-SPANI were characterized by Fourier transform infrared (FTIR) spectroscopy, four-point probe method, and X-ray photoelectron spectroscopy (XPS). The sulfonation rate and degree of LEB-SPANI were found to be dependent upon the acid used in the polymerization step of PANI.关键词
自掺杂聚苯胺/磺酸化/导电性/部分析因设计/中心组合设计Key words
Self-doped polyaniline/Sulfonation/Conductivity/Fractional factorial design/Central composite design分类
矿业与冶金引用本文复制引用
李文亚,胡启章..自掺杂磺酸化聚苯胺之最优化实验设计[J].电化学,2005,11(4):360-368,9.基金项目
the financial support of this work, by the Science Council of Taiwan under contract no. NSC 93-2214-E-194-004, NSC 93-2120-M-194-004, and NSC 93-2214-E-194-010, is gratefully acknowledged. （）
