含能材料2006，Vol.14Issue(5)：361-366,6.
高热稳定性多硝基芳烃的研究
Technologically Attractive High Thermostable Polynitro Arenes
摘要
Abstract
The paper is focused on 2,4,6,4′,6′,2″,4″,6″-octanitro[1,1′,3′,1″]-terphenyl (ONT), 2,2′,2″,4,4′,4″,6,6′,6″-nonanitro[1,1′,3′,1″]-terphenyl (NONA), 2,4,6-tris(2,4,6-trinitrophenyl)-1,3,5-triazine (TPT), N,N-bis(2,4-dinitrophenyl)-2,4,6-trinitroaniline (NTFA), 2,2′,4,4′,6,6′-hexanitrobiphenyl (HNB), 1,3-dinitrobenzene (1,3-DNB) and 1,3,5-trinitrobenzene (TNB). The initiation reactivity of these substances has been studied by means of the data obtained from non-isothermal differential thermal analysis (DTA), their ignition temperatures, impact sensitivity, the data obtained from the Russian manometric method and the detonation characteristics. For comparison, also the data published about 2,2′,2″,2″′,4,4′,4″,4″′,6,6′,6″,6″′-dodecanitro-[1,3′,1′,1″]quaterphenyl (DODECA) have been included. The paper specifies and discusses the relationships between the results of various methods used, inclusive of the forms of modified Evans-Polanyi-Semenov relationship. It has been stated that the technologically most attractive substances, out of those studied, can be ordered in the sequence ONT-TPT-NONA-NTFA according to their increasing thermal reactivity.关键词
organic chemstry/DTA/explosives/ignition temperature/impact sensitivity/thermal reactivity/ONT/NONA/NTFAKey words
organic chemstry/DTA/explosives/ignition temperature/impact sensitivity/thermal reactivity/ONT/NONA/NTFA分类
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Svatopluk ZEMAN,Michal ROH(A)(C)..高热稳定性多硝基芳烃的研究[J].含能材料,2006,14(5):361-366,6.基金项目
The work was carried partly out under the auspices of the Ministry of Education, Youth & Sports of the Czech Republic as a part of its research project No. MSM 0021627501 and partly out under support from the Ministry of Industry & Trade of the Czech Republic as a part of its Research project TANDEM No.FT-TA/049. （）
