硅酸盐学报2008，Vol.36Issue(3)：400-404,5.
掺锶碱硬锰矿固溶体的制备
PREPARATION OF STRONTIUM-DOPED SOLID SOLUTION OF HOLLANDITE
摘要
Abstract
Strontium-doped solid solution of hollandite(SDSSH)was successfully prepared using strontium carbonate(SrCO3),barium carbonate(BaCO3),alumina(Al2O3),and titanium oxide(TiO2)as raw materials by designing formulas and high temperature solid phase reaction.X-ray diffraction,thermogravimetric-differential thermal analysis,scanning electron microscope,and wave dispersive spectroscopy were employed to investigate the synthesis temperature,composition of phases and chemical composition of crystal grains.The formulas of the as-prepared single phase solid solution of hollandite and single phase SDSSH are Ba1+xAl2+2xTi6-2xO16 and SrxBa1Al2+2xTi6-2xO16 respectively.The lowest synthesis temperature of SDSSH is about 1 250℃,and the optimalis 1 300℃.关键词
碱硬锰矿/固溶体/锶/固相反应Key words
hollandite/solid solution/strontium/solid-State reaction分类
资源环境引用本文复制引用
滕元成,周时光,汪建中,张东,赖振宇,孙致平..掺锶碱硬锰矿固溶体的制备[J].硅酸盐学报,2008,36(3):400-404,5.基金项目
国家自然科学基金(10176025)资助项目. （10176025）
