厦门大学学报(自然科学版)2001,Vol.40Issue(2):407-417,11.
水溶性铑膦配合物催化剂的制备、结构和性能
Preparation, Structure and Performance of Water-Soluble Phosphine Rhodium Complexes
袁友珠 1杨意泉 1林国栋 1张鸿斌 1蔡启瑞1
作者信息
摘要
Abstract
The development of biphasic-catalysis involving water-soluble phosphine rhodium complexes catalyzed olefin hydroformylation was discussed, as illustrated by the synthesis, structure stability and deactivation mechanism of water-soluble phosphine ligand coordinated rhodium complexes and supported aqueous-phase catalysts. With this discussion, it is shown that for the biphasic-catalysis system, the molecular design of novel ligand and water-soluble complexes associated with the exploration of new catalysis remains as key issues in the near future.关键词
两相催化/水溶性膦配体/氢甲酰化/负载水相催化剂/催化剂结构分类
化学化工引用本文复制引用
袁友珠,杨意泉,林国栋,张鸿斌,蔡启瑞..水溶性铑膦配合物催化剂的制备、结构和性能[J].厦门大学学报(自然科学版),2001,40(2):407-417,11.