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水溶性铑膦配合物催化剂的制备、结构和性能

袁友珠 杨意泉 林国栋 张鸿斌 蔡启瑞

厦门大学学报(自然科学版)2001,Vol.40Issue(2):407-417,11.
厦门大学学报(自然科学版)2001,Vol.40Issue(2):407-417,11.

水溶性铑膦配合物催化剂的制备、结构和性能

Preparation, Structure and Performance of Water-Soluble Phosphine Rhodium Complexes

袁友珠 1杨意泉 1林国栋 1张鸿斌 1蔡启瑞1

作者信息

  • 1. ,厦门大学化学系,
  • 折叠

摘要

Abstract

The development of biphasic-catalysis involving water-soluble phosphine rhodium complexes catalyzed olefin hydroformylation was discussed, as illustrated by the synthesis, structure stability and deactivation mechanism of water-soluble phosphine ligand coordinated rhodium complexes and supported aqueous-phase catalysts. With this discussion, it is shown that for the biphasic-catalysis system, the molecular design of novel ligand and water-soluble complexes associated with the exploration of new catalysis remains as key issues in the near future.

关键词

两相催化/水溶性膦配体/氢甲酰化/负载水相催化剂/催化剂结构

分类

化学化工

引用本文复制引用

袁友珠,杨意泉,林国栋,张鸿斌,蔡启瑞..水溶性铑膦配合物催化剂的制备、结构和性能[J].厦门大学学报(自然科学版),2001,40(2):407-417,11.

厦门大学学报(自然科学版)

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