农药学学报2007,Vol.9Issue(4):411-414,4.
吡啶衍生物研究(Ⅺ):2-仲丁胺基-5-(2-氯吡啶-4-基)-1,3,4-噻二唑对映异构体的合成及除草活性
Studies on Pyridine Derivatives (Ⅺ):Synthesis and Herbicidal Activities of Both Enantiomers of 2-sec-Butylamino-5-(2-chloropyrid-4-yl)-1,3,4-thiodiazoles
摘要
Abstract
Both enantiomers of 2-sec-butylamino-5-(2-chloropyrid-4-yl)-1,3,4-thiodiazoles (BCPT),a powerful racemic herbicidal compound which was found in previous research,were synthesized from R-and S-butylamine respectively. The preliminary bioassay results showed that three of the thiodiazoles (racemate and enantiomers) were excellent growth inhibitors to both roots and stems of barnyard grass.The S-( + ) enantiomer was the strongest for stem growth inhibition,and R-(-) enantiomer was the weakest. But they had little inhibiting difference on root growth.关键词
吡啶衍生物/仲丁胺/1,3,4-噻二唑,除草活性Key words
pyridine derivatives/sec-butylamine/1,3,4-thiodiazole/herbicidal activity分类
化学化工引用本文复制引用
冉兆晋,车超,李楠,肖玉梅,覃兆海..吡啶衍生物研究(Ⅺ):2-仲丁胺基-5-(2-氯吡啶-4-基)-1,3,4-噻二唑对映异构体的合成及除草活性[J].农药学学报,2007,9(4):411-414,4.基金项目
Supported by the National Science Foundation (No. 20478118) (No. 20478118)
Key Technologies R & D Programme in China (No. 2004BA308A22-1) (No. 2004BA308A22-1)