物理化学学报2009，Vol.25Issue(3)：411-416,6.
以氨基酸为晶体生长控制剂合成多级纳米结构的硫化铟空心微球
Hierarchically Nano-structured Hollow Microspheres Synthesized Using Amino Acids as Crystal Growth Modifiers
摘要
Abstract
Hierarchically nano-structured In2S3 hollow microspheres were synthesized by a hydrothermal method and the hollowing effect was attributed to an Ostwald ripening process. Using different amino acids as crystal growth modifiers, In2S3with different surface morphologies, such as raspberry-like, urchin-like, and flower-like hollow microspheres, were selectively fabricated. The shells of the microspheres were composed of nanosized particles or nanoflakes of In2S3. These results demonstrate that amino acids with different functional groups, such as -NH2, -COOH, and -SH, can induce the formation of different indium sulfide nanostructures. A blue shifted UV band in the UV-Vis spectrum as well as a strong emission at ca 385 nm and a weak emission at ca 364 nm in the photoluminescence (PL) spectrum of InCa hollow microspheres indicate strong quantum confinement because of the presence of nanocrystalline particles. Using different amino acids as crystal growth modifiers, microspheres with different surface morphologies were fabricated. These results demonstrate that amino acids with different functional groups can induce the formation of different indium sulfide nanostructures.关键词
硫化铟/空气球/多级结构/氨基酸/Ostwald ripeningKey words
In2S3/Hollow sphere/Hierarchical structure/Amino acid/Ostwald ripening分类
化学化工引用本文复制引用
邵绍峰,张贵军,周慧静,关乃佳,陈铁红..以氨基酸为晶体生长控制剂合成多级纳米结构的硫化铟空心微球[J].物理化学学报,2009,25(3):411-416,6.基金项目
国家自然科学哈基金(20373029)和教育部新世纪优秀人才支持计划项目(NCCET-07-0448)资助 （20373029）
