陕西科技大学学报(自然科学版)2004，Vol.22Issue(5)：42-47,6.
水热合成羟基磷灰石固溶体中镉离子的优先占位
PREFERENTIAL OCCUPANCY OF CADMIUM IONS IN THE CALCIUM-CADMIUM HYDROXYAPATITE SOLID SOLUTIONS SYNTHESIZED BY HYDROTHERMAL METHOD
朱孔军 1柳泽和道 1岛内理惠 1恩田步武 1梶芳浩二1
作者信息
- 1. 日本高知大学理学部附属水热化学实验所,日本,高知,780-8520
- 折叠
摘要
Abstract
A continuous series of solid solutions in the system of cadmium and calcium hydroxyapatite,Ca10-xCdx ( PO4 )6 ( OH )2 (x = 0 ～ 10 ), was successfully synthesized by both high-temperature mixing method (HTMM) and low-temperature mixing method (LTMM) at 200℃ for 12 hours under hydrothermal conditions. The lattice constants of the solid solutions prepared by both of the methods varied linearly with Cd contents. The Rietveld analysis showed that Cd2+ ions had a slight tendency to occupy M(2) sites preferentially in the solid solutions prepared by both of the two methods.关键词
羟基磷灰石/固溶体/镉离子/水热合成/Rietveld方法Key words
hydroxyapatite/solid solution/cadmium/hydrothermal synthesis/Rietveld method分类
数理科学引用本文复制引用
朱孔军,柳泽和道,岛内理惠,恩田步武,梶芳浩二..水热合成羟基磷灰石固溶体中镉离子的优先占位[J].陕西科技大学学报(自然科学版),2004,22(5):42-47,6.
