四川大学学报（自然科学版）2000，Vol.37Issue(3)：426-431,6.
异羟肟酸过渡金属配合物的合成和催化氧化性能研究
SYNTHESIS AND CATALYTIC OXIDATION PERFORMANCE OF TRANSITION-METAL HYDROXAMATES
吕志凤 1李鸿波 2战风涛 1秦圣英2
作者信息
- 1. 石油大学炼制系，山东东营257062
- 2. 四川大学化学学院，成都610064
- 折叠
摘要
Abstract
A series of trarsition-metal hydroxamates M (L1)2～M(L6)2 were synthesized and characterized. Their catalytic activities in cumene oxidation to cumyl hydroperoxide (CHP) were examined. The influence of substituting groups and their terminal groups in the ligand on catalytic oxidation performance was discussed in comparison with unsubstituted analogue Cu(L7)2. The results show that Cu (L5)2 bearing terminal hydroxyl supported by sufficient long oxyethylene chain is the most excellent one among the total complexes.关键词
异羟肟酸/过渡金属配合物/合成/异丙苯/催化氧化Key words
hydroxamate/transition-metal/synthesis/cumene/catalytic oxidation分类
化学化工引用本文复制引用
吕志凤,李鸿波,战风涛,秦圣英..异羟肟酸过渡金属配合物的合成和催化氧化性能研究[J].四川大学学报（自然科学版）,2000,37(3):426-431,6.
