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La2NiO4+δ透氧膜材料的结构特点与性能

张华 金江 余桂郁 杨南如 施剑林 冯景伟

无机材料学报2001,Vol.16Issue(3):440-446,7.
无机材料学报2001,Vol.16Issue(3):440-446,7.

La2NiO4+δ透氧膜材料的结构特点与性能

Structure and Properties of La2NiO4+δ Oxygen Permeation Membranes

张华 1金江 1余桂郁 1杨南如 1施剑林 2冯景伟2

作者信息

  • 1. 南京化工大学材料学院,
  • 2. 中国科学院上海硅酸盐研究所,
  • 折叠

摘要

Abstract

The structure and the permeability of La2NiO4+δ oxygen permeating membranes were discussed. TEM studies of La2NiO4+δ show that La2NiO4+δ contains a large amount of interstitial oxygen and exhibits a superstructure behavior owing to long range ordering of interstitial oxygen. The oxygen permeation flux through La2NiO4+δ was determined and the relationship between mechanism of oxygen permeability and structure was discussed. The results indicate that the oxygen transportation by interstitial mechanism is easier than that by vacancy mechanism.

关键词

La2NiO4+δ/透氧膜/晶体结构/混合导电性/氧渗透性能

分类

化学化工

引用本文复制引用

张华,金江,余桂郁,杨南如,施剑林,冯景伟..La2NiO4+δ透氧膜材料的结构特点与性能[J].无机材料学报,2001,16(3):440-446,7.

无机材料学报

OA北大核心CSCDSCI

1000-324X

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