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Material Properties of Marine Hydrogenous Ferromanganese Crust and Its Performance in Desulfurization

地质学报(英文版)2006,Vol.80Issue(3):441-450,10.
地质学报(英文版)2006,Vol.80Issue(3):441-450,10.

Material Properties of Marine Hydrogenous Ferromanganese Crust and Its Performance in Desulfurization

Material Properties of Marine Hydrogenous Ferromanganese Crust and Its Performance in Desulfurization

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作者信息

  • 1. State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093;State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing, Jiangsu 210093
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摘要

Abstract

Marine hydrogenous ferromanganese crust, an important metal resource in the future, has significant potential in various applications as a type of natural nano-structured material. By employing scanning electronic microscopy, nitrogen adsorption-desorption isotherm measurement, Xray fluorescence spectrometer and X-ray diffraction methods, the micro-structure, surface properties and chemical composition of several plate-like ferromanganese crusts sampled from the northwestern Pacific were investigated comprehensively. Although obvious differences were observed from different layers, the crust is a typical porous material with high specific surface area, unique pore structure and abundant transition elements. Furthermore, the performance of natural crust in desulfurization process was preliminarily tested in laboratory experiments. The sulfur capacities of the crust are 13.1%and 18.1% at room temperature and 350 ℃, respectively. The crust can be used not only as a metal resource, but also as an environmental material.

关键词

ferromanganese crust/pore structure/surface property/desulfurization

Key words

ferromanganese crust/pore structure/surface property/desulfurization

分类

天文与地球科学

引用本文复制引用

..Material Properties of Marine Hydrogenous Ferromanganese Crust and Its Performance in Desulfurization[J].地质学报(英文版),2006,80(3):441-450,10.

基金项目

This study was supported by the National Natural Science Foundation of China (Grant No. 40373024), the China Association of Research for Oceanic Mineral Resources (Grant No. DY105-01-04-6), and the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20050284043). (Grant No. 40373024)

地质学报(英文版)

1000-9515

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