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正十八烷醇在HOPG上形成自组装膜的吸附特性

钱丽萍 邓文礼

物理化学学报2008,Vol.24Issue(3):443-447,5.
物理化学学报2008,Vol.24Issue(3):443-447,5.

正十八烷醇在HOPG上形成自组装膜的吸附特性

Adsorption Characteristics of Self-assembled 1-Octadecanol Layer on HOPG

钱丽萍 1邓文礼1

作者信息

  • 1. 华南理工大学材料科学与工程学院,广州,510640
  • 折叠

摘要

Abstract

Long-chain alkanol,1-C18H37OH,adsorbed from solution onto highly oriented pyrolytic graphite(HOPG)and formed ordered,oriented monolayer films at room temperature in air. The formation and structure of l-octadecanol self-assembled monolayers(SAMs)on HOPG were examined using scanning tunneling microscopy(STM),contact angle measurement,and X-ray photoelectron spectroscopy (XPS).Our experimental results indicated that 1-octadecanol SAMs grew in domains,With molecules arranged either horizontally or vertically on the substrate.Moreover.the permutation means of the molecule showed relevance to the surface coverage of 1-octadecanol SAMs on the HOPG.

关键词

高定向热解石墨/单分子自组装膜/扫描隧道显微镜/接触角/X射线光电子能谱

Key words

HOPG/SAMs/STM/Contact angle/XPS

分类

化学化工

引用本文复制引用

钱丽萍,邓文礼..正十八烷醇在HOPG上形成自组装膜的吸附特性[J].物理化学学报,2008,24(3):443-447,5.

基金项目

国家自然科学基金(20643001)及广东省科技计划项目(20061311801002)资助 (20643001)

物理化学学报

OA北大核心CSCDCSTPCDSCI

1000-6818

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