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Preparation and Catalytic Oxidation Activity on 2-mercaptoethanol of a Novel Catalytic Cellulose Fibres

YAO Yu-yuan LI Ying-jie CHEN Wen-xing Lü Wang-yang Lü Su-fang XU Min-hong LIU Fan

东华大学学报(英文版)2007,Vol.24Issue(4):451-454,4.
东华大学学报(英文版)2007,Vol.24Issue(4):451-454,4.

Preparation and Catalytic Oxidation Activity on 2-mercaptoethanol of a Novel Catalytic Cellulose Fibres

Preparation and Catalytic Oxidation Activity on 2-mercaptoethanol of a Novel Catalytic Cellulose Fibres

YAO Yu-yuan 1LI Ying-jie 2CHEN Wen-xing 2Lü Wang-yang 2Lü Su-fang 1XU Min-hong 2LIU Fan3

作者信息

  • 1. College of Textiles, Donghua University, Shanghai 200051, China
  • 2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University,Hangzhou 310018, China
  • 3. Key Lab of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Teachers College, Hangzhou 310012,China
  • 折叠

摘要

Abstract

Cobalt tetra(N-carbonylacylic) aminophthalocyanine was supported on cellulose fibres by graft reaction to obtain a novel polymer catalyst, catalytic cellulose fibres (CCF),and the optimal supporting conditions were pH = 6, 80℃,t = 120 min. The catalytic oxidation activity of CCF towards oxidation of 2-mereaptoethanol (MEA) in aqueous solution was investigated. The experimental results demonstrated that CCF had good catalytic oxidation activity on MEA at room temperature, causing no secondary pollution and remaining efficient for the repetitive tests with no obvious decrease of catalytic activity.

关键词

Metallophthalocyanine / cellulose fibres/ 2-merca ptoethanol / polymer catalyst / graft reaction

Key words

Metallophthalocyanine / cellulose fibres/ 2-merca ptoethanol / polymer catalyst / graft reaction

分类

化学化工

引用本文复制引用

YAO Yu-yuan,LI Ying-jie,CHEN Wen-xing,Lü Wang-yang,Lü Su-fang,XU Min-hong,LIU Fan..Preparation and Catalytic Oxidation Activity on 2-mercaptoethanol of a Novel Catalytic Cellulose Fibres[J].东华大学学报(英文版),2007,24(4):451-454,4.

基金项目

Foundation items: National Natural Science Foundation of China (No. 20574061) (No. 20574061)

Program for New Century Excellent Talents in University (NCET-04 -0559) (NCET-04 -0559)

Specialized Research Fund for the Doctoral Program of Higher Education (20060338002) (20060338002)

Program for Chagjiang Scholars Innovetive Research Team in University(IRT 0654) (IRT 0654)

东华大学学报(英文版)

1672-5220

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