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Rheological Behavior of the Guanidio Polyelectrolytes

ZHANG Yu-mei JIANG Jian-ming CHEN Yan-mo

东华大学学报(英文版)2002,Vol.19Issue(4):4-6,3.
东华大学学报(英文版)2002,Vol.19Issue(4):4-6,3.

Rheological Behavior of the Guanidio Polyelectrolytes

Rheological Behavior of the Guanidio Polyelectrolytes

ZHANG Yu-mei 1JIANG Jian-ming 1CHEN Yan-mo1

作者信息

  • 1. College of Material, Dong Hua University, Shanghai, 200051
  • 折叠

摘要

Abstract

The rheological behavior of polyhexamethylene guanidine hydrochloride (PHGC) and polyethylene guanidine stearate (PHGS) has been investigated using the capillary rheometer. It is shown that the polyelectrolyte melts are non-Newtonian of shear. thinning fluid. The melt viscosity, the flow activation energy and the flow temperature are high even if the molecular weight is not high. The melting viscosity of PHGC is higher than that of PHGS at the same experimental conditions. By comparison with the case of PHGS the non-Newtonian index of PHGC is smaller, the flow activation energy and the flow temperature of PHGC are higher, which was caused by the difference in their molecular structure.

关键词

Polyelectrolytes/polymeric guanidine/rheological behavior

Key words

Polyelectrolytes/polymeric guanidine/rheological behavior

分类

信息技术与安全科学

引用本文复制引用

ZHANG Yu-mei,JIANG Jian-ming,CHEN Yan-mo..Rheological Behavior of the Guanidio Polyelectrolytes[J].东华大学学报(英文版),2002,19(4):4-6,3.

基金项目

The research is the Shanghai Down Project. ()

东华大学学报(英文版)

1672-5220

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