云南化工2001,Vol.28Issue(2):4-6,3.
锆基催化剂合成乙酸异辛酯的非等温反应动力学研究
Study on the Kinetics of Synthesis of Iso-octyl Acetate with Zirconium Base Catalyst Under Non-isothermal Condition
吕亮 1段雪 2李峰2
作者信息
- 1. 浙江工业大学浙西分校,浙江衢州 324006
- 2. 北京化工大学应用化学系,北京 100029
- 折叠
摘要
Abstract
Iso-octyl acetate was synthesized with zirconium base catalyst,and the suitable condition of reaction was determined.According to the catalytic characteristic of dynamic method,the equation of reaction rate was deduced under the non-isothermal and volume-varying condition.Kinetic calcuation,showed that the synthetic reaction was consistent with with secondary dynamic model,with activation energy 311.87 kJ/mol,and the frequency factore is 1.9298×1039L*mol-1*min-1.关键词
锆基催化剂/乙酸异辛酯/反应动力学Key words
zirconium base catalyst/iso-octyl acetate/reaction kinetics分类
化学化工引用本文复制引用
吕亮,段雪,李峰..锆基催化剂合成乙酸异辛酯的非等温反应动力学研究[J].云南化工,2001,28(2):4-6,3.