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锆基催化剂合成乙酸异辛酯的非等温反应动力学研究

吕亮 段雪 李峰

云南化工2001,Vol.28Issue(2):4-6,3.
云南化工2001,Vol.28Issue(2):4-6,3.

锆基催化剂合成乙酸异辛酯的非等温反应动力学研究

Study on the Kinetics of Synthesis of Iso-octyl Acetate with Zirconium Base Catalyst Under Non-isothermal Condition

吕亮 1段雪 2李峰2

作者信息

  • 1. 浙江工业大学浙西分校,浙江衢州 324006
  • 2. 北京化工大学应用化学系,北京 100029
  • 折叠

摘要

Abstract

Iso-octyl acetate was synthesized with zirconium base catalyst,and the suitable condition of reaction was determined.According to the catalytic characteristic of dynamic method,the equation of reaction rate was deduced under the non-isothermal and volume-varying condition.Kinetic calcuation,showed that the synthetic reaction was consistent with with secondary dynamic model,with activation energy 311.87 kJ/mol,and the frequency factore is 1.9298×1039L*mol-1*min-1.

关键词

锆基催化剂/乙酸异辛酯/反应动力学

Key words

zirconium base catalyst/iso-octyl acetate/reaction kinetics

分类

化学化工

引用本文复制引用

吕亮,段雪,李峰..锆基催化剂合成乙酸异辛酯的非等温反应动力学研究[J].云南化工,2001,28(2):4-6,3.

云南化工

1004-275X

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