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Synergistic Effect of Tungstate and Benzotriazole on Corrosion Inhibition of Carbon Steel in Solutions Containing Cl-

LI Yan XI Dan-li LU Zhu

东华大学学报(英文版)2004,Vol.21Issue(5):55-59,5.
东华大学学报(英文版)2004,Vol.21Issue(5):55-59,5.

Synergistic Effect of Tungstate and Benzotriazole on Corrosion Inhibition of Carbon Steel in Solutions Containing Cl-

Synergistic Effect of Tungstate and Benzotriazole on Corrosion Inhibition of Carbon Steel in Solutions Containing Cl-

LI Yan 1XI Dan-li 1LU Zhu2

作者信息

  • 1. College of Environmental Science and Engineering, Donghua University, Shanghai 200051
  • 2. Center of Corrosion Prevention, East University of Science and Technology, Shanghai 200237
  • 折叠

摘要

Abstract

The corrosion inhibition of tungstate, benzotriazole (BTA) and their combination in solutions containing Cl- was studied by electrochemical techniques. The results indicated that the inhibition efficiency of tungstate was higher than that of BTA. The efficiency increased with increasing concentration of tungstate or BTA. In the studies of synergistic effect of tungstate and BTA, it had been found that in Ph 9.0 solution, the largest Rt could be obtained with the concentration ratio of tungstate / BTA being 1:1. Lowering the Ph value of solution would reduce the efficiency of inhibitors, especially in binary inhibitors. Increasing the concentration of Cl- accelerated the corrosion of carbon steel in the solutions with various inhibitors, but the influence of Cl- on corroding rate in binary inhibitors was not so strong as in single component. The results of surface analysis showed that W, C, N, O and Fe elements existed in the protecting film formed with binary inhibitors. The thickness of the film was about 12-15nm.

关键词

tungstate/benzotriazole/synergistic effect/EIS/carbon steel

Key words

tungstate/benzotriazole/synergistic effect/EIS/carbon steel

引用本文复制引用

LI Yan,XI Dan-li,LU Zhu..Synergistic Effect of Tungstate and Benzotriazole on Corrosion Inhibition of Carbon Steel in Solutions Containing Cl-[J].东华大学学报(英文版),2004,21(5):55-59,5.

基金项目

The authors acknowledge the support of National Natural Science Foundation of P. R. China ()

东华大学学报(英文版)

1672-5220

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