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首页|期刊导航|哈尔滨工业大学学报(英文版)|Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru

Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru

LI Li ZHANG Mi-lin YUAN Fu-long SHI Ke-ying ZHANG Guo ZHANG Dan

哈尔滨工业大学学报(英文版)2006,Vol.13Issue(5):568-570,3.
哈尔滨工业大学学报(英文版)2006,Vol.13Issue(5):568-570,3.

Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru

Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru

LI Li 1ZHANG Mi-lin 2YUAN Fu-long 1SHI Ke-ying 2ZHANG Guo 2ZHANG Dan2

作者信息

  • 1. Postdoctoral Workstation of Materials Science and Technology, Harbin Engineering University, Harbin 150001 ,China
  • 2. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
  • 折叠

摘要

Abstract

Iron-based perovskite-type compounds modified by Ru were prepared through sol-gel process to study its catalytic activity of NOx direct decomposition at low temperature and evaluate the conversion of NO under the experimental conditions. The catalytic activity of La0.9Ce0.1Fe0.8-nCo0.2RunO3 ( n = 0.01,0.03,0.05,0.07,0.09)series for the NO, NO-CO two components, CO-HC-NO three components were also analyzed. The catalytic investigation evidenced that the presence of Ru is necessary for making highly activity in decomposition of nitric oxide even at low temperature (400 ℃ ) and La0.9Ce0.9Fe0.75Co0.2Ru0.05O3( n = 0. 05 ) has better activity in all the samples, the conversion of it is 58.5%. With the reducing gas (CO, C3 H6 )added into the gas, the catalyst displayed very high activity in decomposition of NO and the conversion of it is 80% and 92. 5% separately.

关键词

iron-based perovskite-type compounds/catalyst modified by Ru/direct decomposition of nitric oxide in low temperature/catalytic activity

Key words

iron-based perovskite-type compounds/catalyst modified by Ru/direct decomposition of nitric oxide in low temperature/catalytic activity

分类

化学化工

引用本文复制引用

LI Li,ZHANG Mi-lin,YUAN Fu-long,SHI Ke-ying,ZHANG Guo,ZHANG Dan..Direct decomposition of nitric oxide in low temperature over iron-based perovskite-type catalyst modified by Ru[J].哈尔滨工业大学学报(英文版),2006,13(5):568-570,3.

基金项目

Sponsored by the National Natural Science Foundation of China( Grant No. 20271019 ()

and 20576027 ) , Natural Science Foundation of Heilongjiang Province( Grant No. B200504 ), Postdoctoral Foundation of Heilongjiang Province( Grant No. LBH-Z05066 ) and Education Department Foundation of Heilongjiang Province(Grant No.11511270). ( Grant No. B200504 )

哈尔滨工业大学学报(英文版)

1005-9113

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