湖南大学学报（自然科学版）2009，Vol.36Issue(5)：57-62,6.
溶剂热辅助法控制合成ZnO纳米结构及其光学性质研究
Synthesis,Controlling and Photoluminescence Study of ZnO Nanostructures Under Solvothermal-Assisted Heat Treatment
摘要
Abstract
ZnC2O4·2H2O nanorods were prepared in a solvothermal-assisted heat treatment method.Different shapes of ZnO, including nano-cornlike-rod, nanosheet and nanochain, were controlled by different annealing temperatures.The near-band ultraviolet emission spectrum of the corn-like ZnO nanorods had one peak at 400 nm under 250 nm excitation at room temperature.A possible mechanism for the formation of the corn-like solvothermal process would decompose to ZnO at high temperature.In the decomposition process, middle product produced some holes at first, and then produced particles which were stringed to nanorods.As the annealing process continued, nanorods adhibited to nanosheets, and then rolled to nanocorn.Finally, nanocorns dispersed to nanochains.关键词
ZnO/纳米材料/形貌控制/发射光谱Key words
ZnO/nanoparticle shape-controlling/emission spectrum分类
通用工业技术引用本文复制引用
杨雷,唐元洪,赵世华,陈江华,胡爱平,王倩,汪国忠..溶剂热辅助法控制合成ZnO纳米结构及其光学性质研究[J].湖南大学学报（自然科学版）,2009,36(5):57-62,6.基金项目
教育部博士点基金资助项目(20070532043) （20070532043）
博士后科学基金资助项目(20080431020) （20080431020）
