高等学校化学学报2001，Vol.22Issue(4)：581-583,3.
杯［4］芳烃硼酸与氨基酸配位作用的荧光光谱研究
Fluorescence Spectral Studies on the Coordination of Calix［4］arenes Bearing Boronic Acid Moieties with Amino Acids
卢奎 1吴养洁 2李永红 2石雅琳 2周稚仙2
作者信息
- 1. 郑州工程学院化学化工系,
- 2. 郑州大学化学系,
- 折叠
摘要
Abstract
Coordination of ten kinds of calix［4］arenes bearing boronic acid moieties with four kinds of amino acids was studied by using fluorescence spectrometry. The stability constants(Ks) of the complexes of calix［4］arenes bearing boronic acid moieties with amino acids and Gibbs free energy change(－ΔG°) of the coordination reactions were calculated according to the modified Hilderbrand-Benesi equation. The results obtained indicated that the coordination abilities and selectivities of L-alanine with calix［4］arenes bearing boronic acid moieties were stronger than that of the other amino acids, and that the above calix［4］arene derivatives could be used for identification of D-alanine.关键词
杯［4］芳烃硼酸/氨基酸/配位作用/荧光光谱分类
化学化工引用本文复制引用
卢奎,吴养洁,李永红,石雅琳,周稚仙..杯［4］芳烃硼酸与氨基酸配位作用的荧光光谱研究[J].高等学校化学学报,2001,22(4):581-583,3.
