中南民族大学学报（自然科学版）2002，Vol.21Issue(4)：5-9,5.
光敏聚酰亚胺合成的新途径(Ⅰ)聚酰胺的氯甲基化反应
Novel Synthesis of Photosensitive Polyimides (Ⅰ) Chloromethylation of Polyimides
摘要
Abstract
Soluble aromatic polyimide was chloromethylated via reaction with chloromethyl methyl ether in the presence of tin(Ⅳ) chloride to produce a new starting material for modification of aromatic polyimides. Chemical structure of the resulting polymer was confirmed by 1H-NMR and FT-IR spectroscopy. The maximum degree of chloromethylation was 181%. Chloromethylated polyimide was stable up to 250 ℃, and soluble in chloroform and THF.关键词
氯甲基化/聚酰亚胺/改性Key words
chloromethylation/polyimide/modification分类
化学化工引用本文复制引用
张爱清,李香丹..光敏聚酰亚胺合成的新途径(Ⅰ)聚酰胺的氯甲基化反应[J].中南民族大学学报（自然科学版）,2002,21(4):5-9,5.基金项目
湖北省自然科学基金重点资助项目(2001ABA009) （2001ABA009）
