华东理工大学学报(自然科学版)2001,Vol.27Issue(1):60-63,112,5.
原子转移自由基聚合制备含氟嵌段共聚物及其性能
Synthesis and Characterization of the Diblock Copolymer of PMMA and PFLUWET
武兵 1李欣欣 1焦健 1吴平平 1韩哲文1
作者信息
摘要
Abstract
A series of diblock copolymers, PMMA-b-PFLUWET have been synthesized by atom transfer radical polymerization (ATRP). The 1H-NMR、19F-NMR、GPC、FTIR were used to characterize copolymer structure. The outstanding surface properties of the low wettability of the copolymers were studied by contact angle measuring for water and oil. The results show that the water and oil repellence increase with the fluorine content in the diblock copolymer. After heat treatment at different temperature, the water and oil repellent properties are increased to a maximum value.关键词
原子转移自由基聚合(ATRP)/甲基丙烯酸甲酯/含氟聚合物/接触角/憎水憎油性分类
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武兵,李欣欣,焦健,吴平平,韩哲文..原子转移自由基聚合制备含氟嵌段共聚物及其性能[J].华东理工大学学报(自然科学版),2001,27(1):60-63,112,5.