四川师范大学学报（自然科学版）2002，Vol.25Issue(6)：606-614,9.
晶体中过渡金属离子零场分裂参量的微观解释Ⅰ:等效哈密顿理论
Microscopic Interpretation of the Zero-field Splitting Parameters of Transition-metal Ions in Crystals Ⅰ:An Effective Hamiltonian Theory
摘要
Abstract
An effective Hamiltonian theory is proposed for the zero-field splitting (ZFS) parameters of transition-metal 3dN ions in crystals by treating the spin-orbit and the spin-spin interactions as perturbations to the electrostatic and the crystal-field potentials. With an excellent convergence, this theory makes it possible to determine every ZFS parmeters of any 3dN ion (N=2～8) in any symmetry having an orbital-singlet ground-state.关键词
过渡金属离子/零场分裂/自旋哈密顿Key words
Transition-metal ions/Zero-field splitting/Spin-Hamiltonian分类
数理科学引用本文复制引用
余万伦..晶体中过渡金属离子零场分裂参量的微观解释Ⅰ:等效哈密顿理论[J].四川师范大学学报（自然科学版）,2002,25(6):606-614,9.基金项目
四川省教育厅重点科研基金资助项目 （）
