四川大学学报(工程科学版)2001，Vol.33Issue(6)：63-66,4.
3-O-没食子酰-D-葡萄糖的合成
Synthesis of 3-O-Galloyl-D-Glucose
摘要
Abstract
As an exploration of synthesizing gallotannins, the natural products with versatile biological activities, 3-o-galloyl-D-glucose was prepared from gallic acid and D-glucose. The phenol hydroxyl groups of gallic acid were protected by benzylation which was cleaved subsequently by 10% palladised charcoal, and the four hydroxyl groups (1,2,4,6) of glucose shielded by isopropylation followed with acid hydrolysis. The structures of 3-o-galloyl-D-glucose and the intermediate product were elucidated with the data of thin-layer chromatography (t.l.c.) and NMR spectrum.关键词
没食子单宁/合成/生理活性分类
化学化工引用本文复制引用
何强,石碧,姚开,罗怡,吕远平..3-O-没食子酰-D-葡萄糖的合成[J].四川大学学报(工程科学版),2001,33(6):63-66,4.基金项目
国家自然科学基金资助项目(29872025) （29872025）
