高等学校化学学报2001，Vol.22Issue(4)：651-653,3.
在i-PrOH-H2O混合溶剂中硫酸镁离子对缔合热力学研究
Thermodynamics of Ion pair of ［MgSO4］0
in i-PrOH Water Mixed Solvent
王洁 1杨家振 1张汝波 1吕殿祯 1张犁天1
作者信息
摘要
Abstract
The standard second ionization constant of sulphuric acid, K2 and the standard association constant of ion pair ［MgSO4］0, KD, in 0.05 molar fraction i-PrOH-water mixture at five temperatures, from 278.15 to 318.15 K were determined from precise emf measurements of different cells without liquid junction. The results have been discussed in term of the solute-solvent interaction and have been compared with those results in water.关键词
离子对/缔合常数/电动势/硫酸镁/硫酸/异丙醇分类
化学化工引用本文复制引用
王洁,杨家振,张汝波,吕殿祯,张犁天..在i-PrOH-H2O混合溶剂中硫酸镁离子对缔合热力学研究[J].高等学校化学学报,2001,22(4):651-653,3.
