硅酸盐学报2008，Vol.36Issue(1)：65-68,4.
介孔分子筛Ti-MCM-41的制备和结构
PREPARATION AND STRUCTURE OF MESOPOROUS MOLECULAR SIEVES Ti-MCM-41
豆茂峰 1金胜明 1付英 1常燕 1关豪元 1杨敏2
作者信息
- 1. 中南大学资源加工与生物工程学院无机材料系,长沙,410083
- 2. 中南大学冶金科学与工程学院,长沙,410083
- 折叠
摘要
Abstract
High-ordered, Ti4+-incorporated, bimodal mesoporous material Ti-MCM-41 was synthesized from glass water and TiCl4 in a water-ethanol-surfactant system and characterized by small-angle X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, N2 adsorption-desorption, and high resolution transmission microscopy techniques. The results show that Ti4+ was in four coordinate in the framework of MCM-41. Furthermore, the zeolite primary units were formed in the framework. The Ti-MCM-41 sample had a bimodal mesoporous structure with the most probable pore sizes of 2.60 nm and 3.85 nm. The specific surface area of Ti-MCM-41 was 1 030 m2/g.关键词
Ti-MCM-41/介孔分子筛/结构表征Key words
Ti-MCM-41/mesoporous molecular sieves/structural characterization分类
化学工程引用本文复制引用
豆茂峰,金胜明,付英,常燕,关豪元,杨敏..介孔分子筛Ti-MCM-41的制备和结构[J].硅酸盐学报,2008,36(1):65-68,4.
