人工晶体学报2009,Vol.38Issue(3):742-745,766,5.
配合物[Cu(C7H5N3O2)2·(H2O)2](NO3)2的合成、晶体结构及荧光性质
Synthesis, Crystal Structure and Fluorescence Properties of Complex [Cu(C7H5N3O2)2·(H2O)2](NO3)2
摘要
Abstract
The title complex [Cu(C7H5N3O2)2·(H2O)2](NO3)2 has been synthesized and was characterized by means of elemental analysis,IR,UV-Vis spectra, and X-ray crystallography. The fluorescence property of the title complex was also studied.The results show that crystal belongs to triclinic with space group of Pī. The cell parameters are a=0.72484(11) nm, b=0.81483(12) nm, c=0.92079(14) nm, α=69.425(2) o, β=78.031(2) o , γ=84.955(2) o, Z=1, F(000)=279. The final R1 = 0.0272, wR2 = 0.0715. The complex has noticeable fluorescence intensity in 739 nm under λex=370 nm.关键词
晶体结构/荧光性质/6-硝基苯并咪唑Key words
crystal structure/fluorescence property/6-nitrobenzimidazole分类
数理科学引用本文复制引用
周永红,田玉鹏,吴杰颖..配合物[Cu(C7H5N3O2)2·(H2O)2](NO3)2的合成、晶体结构及荧光性质[J].人工晶体学报,2009,38(3):742-745,766,5.基金项目
The project supported by Nature Science Foundation of Anhui High School(No.KJ2008B65ZC) (No.KJ2008B65ZC)