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CdS/Cu纳米光催化剂降解废水中的HMX和RDX试验研究

Hamid Reza Pouretedal Mohammad Hossien Keshavarz Mohammad Hasan Yosefi Arash Shokrollahi Abbas Zali

含能材料2008,Vol.16Issue(6):745-752,8.
含能材料2008,Vol.16Issue(6):745-752,8.

CdS/Cu纳米光催化剂降解废水中的HMX和RDX试验研究

Photocatalytic Degradation of HMX and RDX Wastewater with CdS/Cu Nanophotocatalyst

Hamid Reza Pouretedal 1Mohammad Hossien Keshavarz 1Mohammad Hasan Yosefi 1Arash Shokrollahi 1Abbas Zali1

作者信息

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摘要

Abstract

The wastewater with HMX and RDX was treated by photodegradation process in the presence of cadmium sulfide doped with copper as photocatalyst under UV and Vis irradiations. The influence on the degration of Cu% as dopant in CdS/Cu nanoparticles, pH of solution, dosage of photocatalyst and concentration of explosives were studied. The XRD patterns and UV-Vis spectra were used to characterize the nanoparticle. Results show that the degradation efficiency for HMX and RDX wastewater reaches 85%-88% in the presence of Cd0.95Cu0.05S under 180 min UV irradiation. The dosage of 160.0 mg·L-1 of photocatalyst and the pH of 7 are the optimum. A gradual decrease in degradation at the first two cycles is seen.

关键词

cadmium sulfide/nanoparticle/photodegradation/photocatalyst/RDX/HMX

Key words

cadmium sulfide/nanoparticle/photodegradation/photocatalyst/RDX/HMX

分类

武器工业

引用本文复制引用

Hamid Reza Pouretedal,Mohammad Hossien Keshavarz,Mohammad Hasan Yosefi,Arash Shokrollahi,Abbas Zali..CdS/Cu纳米光催化剂降解废水中的HMX和RDX试验研究[J].含能材料,2008,16(6):745-752,8.

含能材料

OA北大核心CSCDCSTPCD

1006-9941

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