广东工业大学学报2000，Vol.17Issue(4)：75-77,3.
从松节油出发，制备紫苏糖的研究
Study on Preparation of Perillartine from Turpentine
刘家良 1邓淑华 2成晓玲3
作者信息
- 1. 广东工业大学成教学院
- 2. 化学工程系
- 3. 实验中心广东广州 510090
- 折叠
摘要
Abstract
Using α-pinene from turpentine oil as material, selenium dioxide as oxidizer, anhydrous alcohol as solvent, myrtenal had been to prepared at rellux temperature and reaction time being 5 hours,the yield being 61% .Isomerization reaction from myrtenal to perillaldehyde carried out at 430℃ and 60kPa passing brass silk catalyst bed in 0.3～0.5s. The oximation reaction of perillaldehyde purified by sodium hydrogen sulfite with hydroxylamine hydrochloride formed perillartine., The total yield was about 20%.
关键词
α-蒎烯/氧化/桃金娘烯醛/异构化/紫苏醛/肟化/紫苏糖Key words
α-pinene/oxidation/myrtenal/ismerization,perillaldehyde/oximation/perillartine分类
化学化工引用本文复制引用
刘家良,邓淑华,成晓玲..从松节油出发，制备紫苏糖的研究[J].广东工业大学学报,2000,17(4):75-77,3.
