天然产物研究与开发2008,Vol.20Issue(5):765-769,5.
无梗五加果化学成分的研究
Studies on the Chemical Constituents of the Fruit of Acanthopanax sessiliflorus (Rupr. et Maxim.) Seem.
安琪 1杨春娟 1宋洋 1于凯 1熊志立 1李发美1
作者信息
摘要
Abstract
Twelve compounds were isolated from the 70% ethanol extract of the fruit of Acanthopanax sessiliflorus (Ru-pr. et Maxim.) Seem. ,which was fractionated on a macroporous resin column by 60% and 30% ethanol. They were i-dentified as scopoletin (1), protocatechuic acid methyl ester (2), quercetin (3), acanthoside B (4), hyperin (5), (-) -pinoresinol-4,4'-di-O-β-D-glucopyranoside (6), chiisanoside (7), 22a-hydroxychiisanoside (8), niduloic acid (9), daucosterol (10) ,acopolin (11) ,and acanthoside D (12) ,by analysis of their spectroscopic data and by comparison with those reported on the literature. Compound 9 was a new natural product. 1,2,6 and 11 were isolated from Araliaceae for the first time and 3 was obtained from Acanthopanax genus for the first time.关键词
五加属/无梗五加/niduloic acid/东莨菪内酯/东莨菪苷/原儿茶酸甲酯/(-)-pinoresinol-4,4'-di-O-β-D-glucopyranoside/槲皮素Key words
Acanthopanax/Acanthopanax sesssiliflorus (Rupr. et Maxim.) Seem./niduloic acid/scopoletin/scopolin/protocatechuic acid methyl ester/(-) -pinoresinol-4,4'-di-O-β-D-glucopyranoside/quercetin分类
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安琪,杨春娟,宋洋,于凯,熊志立,李发美..无梗五加果化学成分的研究[J].天然产物研究与开发,2008,20(5):765-769,5.