人工晶体学报2008，Vol.37Issue(4)：781-785,5.
银螺旋体构筑的三维超分子配合物的合成和晶体结构
Synthesis and Crystal Structure of a Three Dimensional Supramolecular Structure Constructed from Helicate Silver(I) Complex
摘要
Abstract
A new helicate silver (I) complex C38 H29 AgF6 N6 O0.5 P was synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The complex exhibits a singlestranded helix with the Ag (I) atom having a distorted square pyramidal configuration. In the crystal structure C -H…π and π-π stacking interactions between the aromatic groups of the helices lead to a three-dimensional network with 1D channels containing the PF6- anions and H2O molecules. The crystal belongs to monoclinic, space group Cc with α = 1. 7823(7) nm, b = 3. 1382(14) nm, c = 0.8407 (4) nm, β= 116.492(9)°, V= 4.209(3) nm3, Z = 4, Mr = 830.51, dc = 1.311 g · cm3, T = 293(2) K,μ= 0.577 mm-1, F(000) = 1676, R1= 0.0766, wR2 = 0. 1731[I2σ(I)].关键词
螺旋银(I)配合物/多孔网格/晶体结构Key words
helicate silver(I) complex/porous framework/crystal structure分类
数理科学引用本文复制引用
柏龚,李海燕,党东宾..银螺旋体构筑的三维超分子配合物的合成和晶体结构[J].人工晶体学报,2008,37(4):781-785,5.基金项目
Project supported by the National Natural Science Foundation of China ( No. 20701012) （ No. 20701012）
the Foundation of the Education Ministryof China ( No. 207068 ) and the Education Department of Henan Province of China ( No. 2007150003, 2007150011 ) （ No. 207068 ）
