中山大学学报(自然科学版)2009,Vol.48Issue(z2):8-10,3.
中温固体氧化物燃料电池复合阴极材料的性能
Performance of LSCF-CDC Composite Cathode Materials for IT-SOFC
摘要
Abstract
Composite materials La0.6 Sr0.4 Co0.2 Fe0.8 03-δ - Ce0.8Ca0.2O1.9 (LSCF-CDC) were prepared by glycine nitrate process (GNP) and researched as cathode for intermediate temperature SOFC (IT-SOFC), Performance of the materials are measured via dif-ferent methods coming from X-ray powder diffraction (XRD), scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDS), temperature programmed oxygen desorption curves (O2-TPD). The optimum sintering temperature is 1 100 ℃. The av-erage grain size is about 400 nm at 1100℃ and the ratio of elements is in accord with the needed stoiehiometry. The electrical conduc-tivity of LSCF70-CDC (the mole ratio of LSCF and CDC with 7: 3) is the highest at about 700 ℃. The oxygen desorption result sug-gests that there are several types of oxygen in the structure.关键词
LSCF-CDC/复合阴极/电导率/中温固体氧化物燃料电池Key words
LSCF-CDC/composite cathode/electrical conductivity/IT-SOFC分类
信息技术与安全科学引用本文复制引用
陈秀华,张徐民,林航异,于洁,马文会..中温固体氧化物燃料电池复合阴极材料的性能[J].中山大学学报(自然科学版),2009,48(z2):8-10,3.基金项目
国家自然科学基金资助项目(50204007) (50204007)
教育部新世纪优秀人才支持计划基金资助项目(NCET-07-0387) (NCET-07-0387)