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BBDMS-PPV/ITO界面结构ADXPS研究

宋伟杰 朱永法 曹立礼 李展平 王道元 黄维

高等学校化学学报2001,Vol.22Issue(5):836-838,3.
高等学校化学学报2001,Vol.22Issue(5):836-838,3.

BBDMS-PPV/ITO界面结构ADXPS研究

Studies on Interface Structure of BBDMS-PPV/ITO System Using ADXPS Technique

宋伟杰 1朱永法 1曹立礼 1李展平 2王道元 2黄维3

作者信息

  • 1. 清华大学化学系,
  • 2. 日本真空-PHI公司合作实验室,
  • 3. 国立新加坡大学材料与工程研究所,
  • 折叠

摘要

Abstract

We analyzed the structure of buried interface of BBDMS-PPV/ITO system using a high resolution ADXPS technique. A transitional layer structure, whose chemical composition, state and valence band changed gradually from BBDMS-PPV surface of film to substrate ITO, was observed. It was found that O2- ion from ITO diffused into polymer film, interacted with back-bone carbon and formed the carbonyl bonding which could possibly constructed the channel of the carrier on the heterointerface. Indium of ITO also diffused into BBDMS-PPV layer and In(OH)3 was formed during diffusion. The diffusion and reaction between PPV/ITO interface may affect the performance of PLED significantly.

关键词

PPV/ITO界面/界面结构/界面分析/ADXPS

分类

化学化工

引用本文复制引用

宋伟杰,朱永法,曹立礼,李展平,王道元,黄维..BBDMS-PPV/ITO界面结构ADXPS研究[J].高等学校化学学报,2001,22(5):836-838,3.

基金项目

国家自然科学基金 ()

高等学校化学学报

OA北大核心CSCD

0251-0790

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