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CuxC60薄膜紫外-可见吸收光谱研究

吴卫东 张占文 罗江山 唐永建 郑永铭 陆晓明 赵鹏骥

物理化学学报2001,Vol.17Issue(1):83-86,4.
物理化学学报2001,Vol.17Issue(1):83-86,4.

CuxC60薄膜紫外-可见吸收光谱研究

Study of CuxC60 Film UV-Vis Absorption Spectrum

吴卫东 1张占文 1罗江山 1唐永建 1郑永铭 1陆晓明 1赵鹏骥1

作者信息

  • 1. 中国工程物理研究院
  • 折叠

摘要

Abstract

In this paper, the formation of the CuxC60 films has beendescribed briefly. The UV-Vis absorption spectrum of CuxC60 film have been discussed in detail, the electronic structure of CuxC60 film is discussed qualitatively. For x< 1, there exists only Cu+ in the CuxC60 films. However, for x=4, not only Cu+ , but also atom-Cu exists in them. In CuxC60 films three strong peaks have been shiffed compared with that of C60 films. The shift of these strong peaks shows that in the CuxC60 films C60 molecule accepts only one electron and becomes C-60. Because of the existence of the atom-Cu in the CuxC60 films, in visible region there is a wide peak which is the plasmons resonance absorb peak of the Cu-cluster in it.

关键词

CuxC60薄膜,紫外可见吸收光谱,电子结构

引用本文复制引用

吴卫东,张占文,罗江山,唐永建,郑永铭,陆晓明,赵鹏骥..CuxC60薄膜紫外-可见吸收光谱研究[J].物理化学学报,2001,17(1):83-86,4.

基金项目

国家自然科学基金 ()

物理化学学报

OA北大核心CSCDSCI

1000-6818

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