北京大学学报（自然科学版）2002，Vol.38Issue(6)：846-849,4.
硼烷体系中(S)-吲哚醇或(S)-吲哚酸催化的前手性酮的不对称还原
Enantioselective Borane Reduction of Prochiral Ketones Catalyzed by (S)-(indolin-2-yl) methanol or (S)-indoline-2-carboxylic Acid
孙国斌 1裴伟伟 1武永庆 1霍骏 1叶伟平1
作者信息
- 1. 北京大学化学与分子工程学院,北京,100871
- 折叠
摘要
Abstract
An enantioselective borane reduction of prochiral ketones directly catalyzed by (S)-(indolin-2-yl)methanol or (S)-indoline-2-carboxylic acid was examined and the resultant chiral secondary alcohols with 82%～87% enantiomeric excess were obtained.关键词
不对称硼烷还原/(S)-吲哚醇/(S)-吲哚酸/酮Key words
asymmetric borane reduction/(S)-(indolin-2-yl)methanol/(S)-indoline-2-carboxylic acid/ketones分类
化学化工引用本文复制引用
孙国斌,裴伟伟,武永庆,霍骏,叶伟平..硼烷体系中(S)-吲哚醇或(S)-吲哚酸催化的前手性酮的不对称还原[J].北京大学学报（自然科学版）,2002,38(6):846-849,4.
