安徽农业科学2009,Vol.35Issue(19):8835-8836,8839,3.
菜籽油常压水解制备脂肪酸的研究
Preparation of Fatty Acid by Hydrolysis of Rapeseed Oil under Normal Pressure
摘要
Abstract
[Objective] The research aimed to take the rapeseed oil as raw material for hydrolysis preparation of fatty acid atmospheric pressure.[Method] Fatty acid was produced by hydrolysis of rapeseed oil under normal pressure at the temperature of (95±5)℃.Effects of ratio of oil to water, amount of catalyst and emulsification and time on reaction were studied.[Result] The optimal parameter was as follows: amount of emulsification 4%(W/W), amount of catalyst 15%(W/W), weight ratio of oil to water 1∶ 2, hydrolysis time 17 h.Under the conditions, the acid value of hydrolyzed Jatropha curcas oil reached 180.3 mg/g.[Conclusion] The fatty acids which were commonly used in industry could be produced under atmospheric pressure by hydrolyzing the rapeseed oil.And the conversion rate could reach 93.8%.关键词
菜籽油/十二烷基苯磺酸钠/水解/脂肪酸Key words
Rapeseed oil/Sodium dodecylbenzene sulfonate/Hydrolysis/Fatty acid分类
化学化工引用本文复制引用
张伦,张无敌,尹芳,李建昌,田光亮,徐锐..菜籽油常压水解制备脂肪酸的研究[J].安徽农业科学,2009,35(19):8835-8836,8839,3.基金项目
国家自然科学基金(90610034)、国家863项目(2007AA02Z 231911)和教育部春晖计划联合资助. (90610034)