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菜籽油常压水解制备脂肪酸的研究

张伦 张无敌 尹芳 李建昌 田光亮 徐锐

安徽农业科学2009,Vol.35Issue(19):8835-8836,8839,3.
安徽农业科学2009,Vol.35Issue(19):8835-8836,8839,3.

菜籽油常压水解制备脂肪酸的研究

Preparation of Fatty Acid by Hydrolysis of Rapeseed Oil under Normal Pressure

张伦 1张无敌 1尹芳 1李建昌 1田光亮 1徐锐1

作者信息

  • 1. 云南师范大学,云南省农村能源工程重点实验室,云南昆明,650092
  • 折叠

摘要

Abstract

[Objective] The research aimed to take the rapeseed oil as raw material for hydrolysis preparation of fatty acid atmospheric pressure.[Method] Fatty acid was produced by hydrolysis of rapeseed oil under normal pressure at the temperature of (95±5)℃.Effects of ratio of oil to water, amount of catalyst and emulsification and time on reaction were studied.[Result] The optimal parameter was as follows: amount of emulsification 4%(W/W), amount of catalyst 15%(W/W), weight ratio of oil to water 1∶ 2, hydrolysis time 17 h.Under the conditions, the acid value of hydrolyzed Jatropha curcas oil reached 180.3 mg/g.[Conclusion] The fatty acids which were commonly used in industry could be produced under atmospheric pressure by hydrolyzing the rapeseed oil.And the conversion rate could reach 93.8%.

关键词

菜籽油/十二烷基苯磺酸钠/水解/脂肪酸

Key words

Rapeseed oil/Sodium dodecylbenzene sulfonate/Hydrolysis/Fatty acid

分类

化学化工

引用本文复制引用

张伦,张无敌,尹芳,李建昌,田光亮,徐锐..菜籽油常压水解制备脂肪酸的研究[J].安徽农业科学,2009,35(19):8835-8836,8839,3.

基金项目

国家自然科学基金(90610034)、国家863项目(2007AA02Z 231911)和教育部春晖计划联合资助. (90610034)

安徽农业科学

OA北大核心CSTPCD

0517-6611

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