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首页|期刊导航|东华大学学报(英文版)|Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)

Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)

咸春颖 赵曙辉 朱龙观 谢学鹏

东华大学学报(英文版)2001,Vol.18Issue(3):88-90,3.
东华大学学报(英文版)2001,Vol.18Issue(3):88-90,3.

Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)

Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)

咸春颖 1赵曙辉 1朱龙观 2谢学鹏2

作者信息

  • 1. College of Chemistry and Chemical Engineering, Dong Hua University, Shanghai, 200051
  • 2. Department of Chemistry, Zhejiang University, Hangzhou, 310027
  • 折叠

摘要

Abstract

Many trinary lanthanide complexes have been studied. However, few mixed anion complexes with bidentate heterocyclic amines were synthesized. We synthesized mixed anion complexes Ln ( CHi CICO0 )2 (NO3) (phen) which was determined by elemental analyses. The IR spectra analyses indicate that NO3 ,CH2 C1CO0- and phen are coordinated with Ln. The molar conductances of the complexes at 10-3 mol. L-1 were founded to be between 32.4 and 35.8 S. cma@mol- 1 , suggesting the nonelectrolytes in N Dimethylformamide. And we determined the fluorescent spectra Eu(CH2C1COO)2(NO3) ( phen ) and ESR spectra of Gd( CH2 ClC00 )2 ( NOs ) ( phen ) .

关键词

Lantnthanide/Quaternary Complex/Synthesis/Characterization

Key words

Lantnthanide/Quaternary Complex/Synthesis/Characterization

分类

化学化工

引用本文复制引用

咸春颖,赵曙辉,朱龙观,谢学鹏..Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)[J].东华大学学报(英文版),2001,18(3):88-90,3.

基金项目

Sponsored by Junior Foundation of Municipal Education Commission of Shanghai ()

东华大学学报(英文版)

1672-5220

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