首页|期刊导航|东华大学学报(英文版)|Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)
东华大学学报(英文版)2001,Vol.18Issue(3):88-90,3.
Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)
Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)
摘要
Abstract
Many trinary lanthanide complexes have been studied. However, few mixed anion complexes with bidentate heterocyclic amines were synthesized. We synthesized mixed anion complexes Ln ( CHi CICO0 )2 (NO3) (phen) which was determined by elemental analyses. The IR spectra analyses indicate that NO3 ,CH2 C1CO0- and phen are coordinated with Ln. The molar conductances of the complexes at 10-3 mol. L-1 were founded to be between 32.4 and 35.8 S. cma@mol- 1 , suggesting the nonelectrolytes in N Dimethylformamide. And we determined the fluorescent spectra Eu(CH2C1COO)2(NO3) ( phen ) and ESR spectra of Gd( CH2 ClC00 )2 ( NOs ) ( phen ) .关键词
Lantnthanide/Quaternary Complex/Synthesis/CharacterizationKey words
Lantnthanide/Quaternary Complex/Synthesis/Characterization分类
化学化工引用本文复制引用
咸春颖,赵曙辉,朱龙观,谢学鹏..Synthesis and Characterization of Quaternary Complexes Ln ( CH2 ClCO0 ) 2 ( NO3 ) ( phen)[J].东华大学学报(英文版),2001,18(3):88-90,3.基金项目
Sponsored by Junior Foundation of Municipal Education Commission of Shanghai ()