应用化学2001，Vol.18Issue(1)：9-11,3.
有机/无机纳米杂化材料载体化钛催化剂的聚合研究Ⅱ.间同聚苯乙烯制备
Study on the Polymerization with Organic/Inorganic Hybrid-Supported Titanium Catalysts Ⅱ.Styrene Polymerizaton
摘要
Abstract
The use of organic/inorganic hybrid materialspoly(styrene-co-maleic anhydride)/SiO2 as the support for titanium catalysts in styrene polymerization was studied. Results indicated that at 70 ℃ the activity of the inorganic/organic hybrid supported catalysts would reached a maximum; 1.49×106 g/(mol*h). With increase in reaction temperature, the molecular weight of polymer decreased, and the polydispersity was much wider. DSC and FTIR measurements showed that the product was syndiotatic polystyrene.关键词
杂化材料/载体化钛催化剂/间同聚苯乙烯/定向聚合分类
化学化工引用本文复制引用
朱宁,唐涛,陈辉,于广谦,冯之榴,黄葆同..有机/无机纳米杂化材料载体化钛催化剂的聚合研究Ⅱ.间同聚苯乙烯制备[J].应用化学,2001,18(1):9-11,3.基金项目
国家重点基础研究专项经费资助项目 （）
