发光学报2007，Vol.28Issue(6)：930-934,5.
稀土钕-丙烯酸-草酸配合物的合成、表征及荧光性能
Synthesis, Characterization and Fluorescence Property of Rare-earth Neodymium with Oxalic Acid and Acrylic Acid
摘要
Abstract
The novel ternary solid complex of rare earth neodymium (Nd) with oxalic acid (OA) and acroleic acid (AA) was synthesized. The chemical structure and the properties of the complex were characterized by using the element analysis, FT-IR, UV-Vis spectrum, thermal gravimetric analysis (TGA) and fluorescence spectrum. Their composition was determined to be [Nd(OOC-COO) (CH2CH-COO)]·3H2O. The TGA result showed that the complex has excellent thermal stability. The fluorescence spectrum suggested that the innovative complex containing rare-earth ions (Nd3+), with strong characteristic emissions due to the 4G5/2+2G7/2-4I9/2 transition of Nd3+ ions, is a kind of photoluminescence materials.关键词
稀土/配合物/荧光光谱Key words
rare-earth/ complex/ fluorescence spectra分类
数理科学引用本文复制引用
邱凤仙,徐红良,笪祖林,杨冬亚..稀土钕-丙烯酸-草酸配合物的合成、表征及荧光性能[J].发光学报,2007,28(6):930-934,5.基金项目
江苏省博士后科研资助计划(0602037B) （0602037B）
江苏省高校自然科学基金(05KJB150016) （05KJB150016）
江苏大学高级人才基金(06JDG015)资助项目 Project supported by the Jiangsu Planned Projects for Postdoctoral Research Funds(0602037B) （06JDG015）
the Natural Science of Jiangsu Education (05KJB150016) and the Fund of Jiangsu University (06JDG015) （05KJB150016）
