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Effect of LiCl in Polymer Solution on the Instable Part of Electrospinning Nanofibers: Theoretical Analysis and Experimental Verification

QIN Xiao-hong JIA Lin LI Ni

东华大学学报(英文版)2010,Vol.27Issue(3):312-315,4.
东华大学学报(英文版)2010,Vol.27Issue(3):312-315,4.

Effect of LiCl in Polymer Solution on the Instable Part of Electrospinning Nanofibers: Theoretical Analysis and Experimental Verification

Effect of LiCl in Polymer Solution on the Instable Part of Electrospinning Nanofibers: Theoretical Analysis and Experimental Verification

QIN Xiao-hong 1JIA Lin 2LI Ni3

作者信息

  • 1. Key Laboratory of Textile Science & Technology, Ministry of Education, Donghua University, Shanghai 201620, China
  • 2. College of Materials and Textiles, Zhejiang Science & Technology University, Hangzhou 310018, China
  • 折叠

摘要

Abstract

In this paper, the theoretical analysis proves that the relationship between radius r of jet and the axial distance z from the onset of whipping instability follows an allometric law in the form r ∝ z-1/4 whatever surface charge parameter a is. Polyvinylalcohol (PVA) was used to study the effect of surface charge on the variation of jet diameter with axial coordinate after the onset of whipping instability during electrospinning by adding LiCI. The experiment shows that the relationship between radius r of jet and the axial distance z from the onset of whipping instability also follows the law in the form r∝ z-1/4 whenthe content of LiCl is from 0.2 wt% to 4 wt%. That is, the law does not depend upon the content of salt, and the theoretical prediction agrees quite well with the experimental data.

关键词

electrospinning/Polyvinylalcohol ( PVA )/scaling/allometry

Key words

electrospinning/Polyvinylalcohol ( PVA )/scaling/allometry

分类

化学化工

引用本文复制引用

QIN Xiao-hong,JIA Lin,LI Ni..Effect of LiCl in Polymer Solution on the Instable Part of Electrospinning Nanofibers: Theoretical Analysis and Experimental Verification[J].东华大学学报(英文版),2010,27(3):312-315,4.

基金项目

National Natural Science Foundations of China(No. 50973014, No. 10902099) (No. 50973014, No. 10902099)

the Author of National Excellent Doctoral Dissertation of P.R. China (No. 200961) (No. 200961)

Shanghai Rising-Star Program(No. 10QA1400100) (No. 10QA1400100)

Fok Ying Tong Education Foundation(No. 121071) (No. 121071)

the Fundamental Research Funds for the Central Universities, China(No. 9D10117) (No. 9D10117)

东华大学学报(英文版)

1672-5220

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