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葡萄糖改性水性聚氨酯的合成与表征

杨燕 沈一丁 赖小娟 王磊

化工进展2011,Vol.30Issue(2):386-389,4.
化工进展2011,Vol.30Issue(2):386-389,4.

葡萄糖改性水性聚氨酯的合成与表征

Synthesis and characterization of waterborne polyurethane modified by glucose

杨燕 1沈一丁 1赖小娟 1王磊1

作者信息

  • 1. 陕西科技大学教育部轻化工助剂化学与技术重点实验室,陕西,西安,710021
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摘要

Abstract

Waterborne polyurethane ( WPU ) emulsion was synthesized by a prepolymer process using dimethylol propionic acid (DMPA) and glucose as hydrophilic agent and crosslinking agent,respectively. The structure of the films was confirmed by means of FTIR. The test results indicated that glucose was introduced into the main chain of polyurethane. TG analysis indicated that the thermal stability of WPU films modified with glucose was improved. The effect of glucose content on the mechanical properties of the WPU films was studied. The results showed that the properties of WPU films were improved with increasing weight of PG. When glucose content increased from 0 to 4.68%,elongation at break decreased from 529.9% to 276.4% and tensile strength increased from 10.9 MPa to 24.2 MPa.

关键词

葡萄糖/水性聚氨酯/合成/表征

Key words

glucose/ waterbome polyurethane/ synthesis/ characterization

分类

化学化工

引用本文复制引用

杨燕,沈一丁,赖小娟,王磊..葡萄糖改性水性聚氨酯的合成与表征[J].化工进展,2011,30(2):386-389,4.

基金项目

国家自然科学基金(20876093,50973057)及陕西省自然科学基础研究计划项目(2010JQ6013). (20876093,50973057)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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