四川师范大学学报（自然科学版）2011，Vol.34Issue(1)：91-94,4.DOI:10.3969/j.issn.1001-8395.2011.01.019
系列樟脑型β-二酮化合物的合成
Synthesis of a Series of Camphor-type β-dione Compounds
摘要
Abstract
The α-methylene of camphor is very hard to be activated because of the steric hindrance.In this paper, a series of camphor-type β-dione compounds are synthesized by using D( + )-camphor as starting material, ethylene glycol diethyl ether as solvent,and sodium hydride as a basic catalyst.The target compounds are obtained in a yield of 30％ ～58.3％ and are characterized by 1H NMR and MS.The influences of solvent, basic catalyst and purification method on the reaction are also discussed.关键词
D(+)-樟脑/合成/樟脑型β-二酮Key words
D(+)-camphor/ synthesis/ camphor-type β-dione分类
化学化工引用本文复制引用
谢运,骆开均,蒋世平,徐玲玲..系列樟脑型β-二酮化合物的合成[J].四川师范大学学报（自然科学版）,2011,34(1):91-94,4.基金项目
国家自然科学基金(21072141)和四川省教育厅自然科学重点基金(08ZA040)资助项目 （21072141）
