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镍铝层状双氢氧化物正极锌镍电池充放电性能

杨建锋 周震涛

电源技术2011,Vol.35Issue(2):189-191,3.
电源技术2011,Vol.35Issue(2):189-191,3.

镍铝层状双氢氧化物正极锌镍电池充放电性能

Charge-discharge performance of Zn-Ni cell with Ni-Al layered doublehydroxides cathode

杨建锋 1周震涛2

作者信息

  • 1. 华南理工大学,材料科学与工程学院,广东,广州,510640
  • 2. 深圳市迪凯特集团,研发中心,广东,深圳,518118
  • 折叠

摘要

Abstract

Ni-Al layered double hydroxides were prepared with spray technique on the base of chemical co-precipitation. The structure of the product was analyzed and the physical properties were tested. Moreover, it was used as cathode active material to manufacture Zn-Ni cell,and then the charge-discharge performance was studied. The experimental results show that the sample has single α phase crystal structure and irregular particle morphology. Its specific surface area reaches 14.1 m2/g and the average particle size is 18.38 μm. The cell has obviously better cycle stability, higher discharge capacity and voltage plateau than that with spherical β-Ni(OH)2 cathode. The average discharge capacity reaches 287.4 mAh/g within 120 cycles at 1 C rate, and the median discharge voltage attains 1.688 V.

关键词

镍铝层状双氢氧化物/锌镍电池/正极活性物质/充放电性能

Key words

Ni-Al/ layered double hydroxides/ Zn-Ni cell/ cathodic active material/ charge-discharge performance

分类

信息技术与安全科学

引用本文复制引用

杨建锋,周震涛..镍铝层状双氢氧化物正极锌镍电池充放电性能[J].电源技术,2011,35(2):189-191,3.

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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