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LiFePO4/C复合材料中的碳源研究

何文英 胡国荣 彭忠东 杜柯

电源技术2011,Vol.35Issue(2):158-161,4.
电源技术2011,Vol.35Issue(2):158-161,4.

LiFePO4/C复合材料中的碳源研究

Carbon source in LiFePO4/C composite cathode material

何文英 1胡国荣 1彭忠东 1杜柯1

作者信息

  • 1. 中南大学冶金科学与工程学院,湖南,长沙,410083
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摘要

Abstract

Olivine LiFePO4/C composite cathode materials were synthesized by a solid state method using sucrose,phenolic resin and polypropylene as carbon sources respectively. The effects of different carbon sources on the performance of as-synthesized cathode materials were investigated and analyzed. The crystal structure and the electrochemical performance were characterized by XRD, SEM, Raman spectrum, charge-discharge testing and AC impedance. The results demonstrate that the composite material carbon-coated by polypropylene has the most excellent electrochemical performance which has an initiative capacity of 154.9 mAh/g at 0.1 Cand 131.3 mAh/g at 2 Cand the capacity is 130.1 mAh/g after 30 cycles at 2 C.

关键词

LiFePO4/C复合材料/碳源/碳包覆/电化学性能

Key words

LiFePO4/C composite cathode material/ carbon sources/ carbon-coated/ electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

何文英,胡国荣,彭忠东,杜柯..LiFePO4/C复合材料中的碳源研究[J].电源技术,2011,35(2):158-161,4.

基金项目

国家科技支撑计划资助项目(2007BAE12B01-1),湖南省科技计划资助项目(2009GK3150) (2007BAE12B01-1)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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