色谱2011，Vol.29Issue(1)：42-48,7.DOI:10.3724/SP.J.1123.2011.00042
气相色谱-质谱法测定聚氯乙烯包装材料和食品模拟物中的46种增塑剂
Determination of 46 plasticizers in food contact polyvinyl chloride packaging materials and their migration into food simulants by gas chromatography- mass spectrometry
摘要
Abstract
A gas chromatography-mass spectrometry (GC-MS) method was developed for the determination of 46 plasticizers in food contact polyvinyl chloride (PVC) packaging materials and their migration into food simulants, i.e. water, 3％ acetic acid, 10％ ethanol and olive oil.Plasticizers in the PVC packaging materials, aqueous food simulants and olive oil food simulants were extracted by the dissolution-precipitation, liquid-liquid extraction and gel permeation chromatography (GPC) approaches, respectively. The extracts were analyzed by GC-MS in selective ion monitoring (SIM) mode and quantified using the external standard method. The calibration curves were linear in the ranges of 0.1 - 2.0 mg/L with the correlation coefficients of 0. 991 0 -0. 999 9. The limits of detection were from 0.005 mg/kg to 0.05 mg/kg ( S/N = 5 ).The recoveries at 3 spiked levels were 69.51％ - 107.21％ and the relative standard deviations ( RSDs, n =6) ranged from 3.53％ to 18.95％. These results show that this method is fast, sensitive and accurate for the qualitative and quantitative determination of plasticizers in food contact plastic products and 4 types of food simulants.关键词
气相色谱-质谱/增塑剂/迁移量/塑料食品包装/食品模拟物分类
化学化工引用本文复制引用
郭春海,薄海波,段文仲,贾海涛,陈瑞春,马育松,艾连峰..气相色谱-质谱法测定聚氯乙烯包装材料和食品模拟物中的46种增塑剂[J].色谱,2011,29(1):42-48,7.基金项目
国家质监总局科研计划项目(No. 2008IK116). （No. 2008IK116）
