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低品质蓝宝石高温扩散法工艺改善研究

陈征 刘学良 郭守国 宋晶晶

矿产保护与利用Issue(1):22-27,6.
矿产保护与利用Issue(1):22-27,6.

低品质蓝宝石高温扩散法工艺改善研究

Study on Low- Quality Sapphire Improving Technique by High- Temperature Diffusion Method

陈征 1刘学良 2郭守国 2宋晶晶2

作者信息

  • 1. 上海建桥学院宝石教研室,上海,201319
  • 2. 华东理工大学材料科学与工程学院,上海,200237
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摘要

Abstract

High- temperature diffusion method had been used to design an improving technique with a foundation of twice heat - treatment to change low - quality corundum into black sapphire.With the optimum temperature, the reagent pretreatment and adding effective flux, low -quality corundum had been changed into black sapphire. EDS spectra and UV -VIS spectra had been used to test the samples. The analysis showed that the mechanism of color enhancement is adding Fe3 +as well as Fe2+ and Ti4+ to inhibit absorption by each other as to make sample totally black. And it also showed that heating temperature and concentration gradient of coloring ions are main factors for diffusion.

关键词

低品质刚玉/黑色蓝宝石/高温扩散/一次热处理/二次热处理/温度/致色离子

Key words

low - quality corundum/ black sapphire/ high - temperature diffusion/ first - timeheat - treatment/ second - time heat - treatment/ temperature/ coloring ions

分类

天文与地球科学

引用本文复制引用

陈征,刘学良,郭守国,宋晶晶..低品质蓝宝石高温扩散法工艺改善研究[J].矿产保护与利用,2011,(1):22-27,6.

矿产保护与利用

OACSTPCD

1001-0076

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