陕西科技大学学报(自然科学版)2011,Vol.29Issue(1):38-42,5.
L型聚乳酸/氯化钙共混物热分解机理研究
STUDY ON THERMAL DEGRADATION MECHANISM AND PYROLYSIS OF THE BLENDS OF L-POLY(LACTIC ACID) AND CALCIUM CHLORIDE
苏秀霞 1姚宝晶1
作者信息
- 1. 陕西科技大学化学与化工学院,陕西,西安,710021
- 折叠
摘要
Abstract
The poly(L-lactic acid)(PLLA) cast film was made using purified PLLA and calcium chloride, the purified CHCl3 acted as solvent.The specimen was investigated by modulated thermogravmitry analysis, the results showed the PLLA pyrolysis had one step, at the same time we got the Ea, Z and ln(rate ratio).The structures low molecular compounds were determined by NMR and FTIR.The data supported that during the pyrolysis process,the furan, cyclopropanes and lactic acid were produced except low molecular PLA.关键词
聚乳酸/热裂解/调制式热重/热分解机理分类
化学化工引用本文复制引用
苏秀霞,姚宝晶..L型聚乳酸/氯化钙共混物热分解机理研究[J].陕西科技大学学报(自然科学版),2011,29(1):38-42,5.