高等学校化学学报2011，Vol.32Issue(3)：721-725,5.
AM-6分子筛的快速合成及原子线形成机理研究
UV Raman Spectroscopic Studies on Rapid Synthesis of AM-6 Zeolite and Formation Mechanism of —V O V— Atomic Wires
摘要
Abstract
A rapid synthesis(4 h) method of AM-6 zeolite was reported. The effects of the n(K+ )/n(V4+) ratio and the pH value of the initial gel on the purity and crystallinity of AM-6 zeolite were investigated. The synthesis conditions optimize at n ( K + )/n ( V4+ ) = 3 and pH = 12.5. The formation mechanism of the V—O—V— atomic wires in AM-6 was monitored by UV Raman spectroscopy in combination with UV-Vis spectroscopy and X-ray diffraction patterns. It turns out that the formation of the VO3- chains composed of cornet-sharing VO4 in the silicate gel plays an important role in the formation of—V—O—V— atomic wires in AM-6 crystals.关键词
AM-6分子筛/紫外拉曼光谱/合成机理/原子线Key words
AM-6 zeolite/ UV Raman spectroscopy/ Synthesis mechanism/ Atomic wire分类
化学化工引用本文复制引用
郭美玲,范峰滔,郭强,冯兆池,李灿..AM-6分子筛的快速合成及原子线形成机理研究[J].高等学校化学学报,2011,32(3):721-725,5.基金项目
国家"九七三"计划项目(批准号:2009CB623507)和国家自然科学基金(批准号:20773118,21003122)资助. （批准号:2009CB623507）
