化工学报2011,Vol.62Issue(1):142-146,5.
Ni-Cu合金电极上苯甲醇的选择性电氧化
Selective electro-oxidation of benzyl alcohol on Ni-Cu alloy electrodes
摘要
Abstract
The Ni-Cu alloy electrodes were prepared by constant current electrodeposition under different conditions. The morphology of Ni-Cu alloy was characterized by SEM. The selective electro-oxidation of benzyl alcohol in alkaline solution was studied with cyclic voltammograms and in-situ FTIR spectroscopy. The Ni-Cu alloy electrode showed the best electro-catalytic activity while the electrodeposition time was 10 min, cathode current density was 4 A · dm -2, and the electrodeposition temperatures was 45℃. Ni-Cu alloy electrodes showed excellent chemical stability and better catalytic activity than pure Ni or Cu electrode.关键词
电氧化/Ni-Cu合金电极/苯甲醇Key words
electro-oxidation/ Ni-Cu alloy electrode/ benzyl alcohol分类
化学化工引用本文复制引用
马淳安,廖艳梅,朱英红,吴玲玲..Ni-Cu合金电极上苯甲醇的选择性电氧化[J].化工学报,2011,62(1):142-146,5.基金项目
教育部博士点基金项目(20070337001). (20070337001)