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Ni-Cu合金电极上苯甲醇的选择性电氧化

马淳安 廖艳梅 朱英红 吴玲玲

化工学报2011,Vol.62Issue(1):142-146,5.
化工学报2011,Vol.62Issue(1):142-146,5.

Ni-Cu合金电极上苯甲醇的选择性电氧化

Selective electro-oxidation of benzyl alcohol on Ni-Cu alloy electrodes

马淳安 1廖艳梅 1朱英红 1吴玲玲1

作者信息

  • 1. 浙江工业大学化学工程与材料学院,绿色化学合成技术国家重点实验室培育基地,浙江,杭州,310032
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摘要

Abstract

The Ni-Cu alloy electrodes were prepared by constant current electrodeposition under different conditions. The morphology of Ni-Cu alloy was characterized by SEM. The selective electro-oxidation of benzyl alcohol in alkaline solution was studied with cyclic voltammograms and in-situ FTIR spectroscopy. The Ni-Cu alloy electrode showed the best electro-catalytic activity while the electrodeposition time was 10 min, cathode current density was 4 A · dm -2, and the electrodeposition temperatures was 45℃. Ni-Cu alloy electrodes showed excellent chemical stability and better catalytic activity than pure Ni or Cu electrode.

关键词

电氧化/Ni-Cu合金电极/苯甲醇

Key words

electro-oxidation/ Ni-Cu alloy electrode/ benzyl alcohol

分类

化学化工

引用本文复制引用

马淳安,廖艳梅,朱英红,吴玲玲..Ni-Cu合金电极上苯甲醇的选择性电氧化[J].化工学报,2011,62(1):142-146,5.

基金项目

教育部博士点基金项目(20070337001). (20070337001)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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