广西科学2011，Vol.18Issue(1)：61-63,3.
2-氯苯氧乙酸的催化合成研究
Catalytic Synthesis of 2-Chlorophenoxyacetic Acid
摘要
Abstract
The use of cetyltrimethylammonium bromide catalyzed chloroacetate and 2-chlorophenol synthesis of 2-chlorophenoxyacetic acid. Cetyltrimethylammonium bromide has a higher catalytic activity and can accelerate the synthesis of 2-chlorophenoxyacetic acid. The reaction is studied on 2-chlorophenol and chloroacetic acid molar ratio,catalyst amount, reaction time and temperature on yield,and the performance of repeated use of catalyst. The best reaction conditions are as follows: at 85℃,2-chlorophenol and chloroacetate molar ratio of 1 ： 4,catalyst weight of 0.3g,reaction time of 3.5h, which get 2-chlorophenoxyacetic acidproduction rate of 50.50 ％. This catalyst is characterized by small amount, easy recovery,and can be reused.关键词
2-氯苯氧乙酸/氯乙酸/2-氯苯酚/十六烷基三甲基溴化铵/合成Key words
2-chlorophenoxyacetic acid/ chloroacetate/ 2-chlorophenol/ cetyltrimethylammonium bromide/ synthesis分类
化学化工引用本文复制引用
农邦写,黄锁义..2-氯苯氧乙酸的催化合成研究[J].广西科学,2011,18(1):61-63,3.基金项目
广西自然科学基金课题(桂科自0899022) （桂科自0899022）
广西教育厅课题(2007101LX149). （2007101LX149）
