电化学2011，Vol.17Issue(1)：84-87,4.
多层聚吡咯-铂复合膜电极的甲醇电催化氧化
Electrooxidation of Methanol on Multilayer Films of Polypyrrole-Platinum Electrode
摘要
Abstract
Multilayer films of polypyrrole-platinum electrode were fabricated by cyclic voltammetric technique.Electro-oxidation of methanol on this electrode was investigated with the aid of cyclic voltammetry and chrono-amperometry. Results demonstrated that the multilayer of polypyrrole-platinum electrode behaved better electro-catalytic performance for electro-oxidaton of methanol and better poison resistant. Furthermore, with the increase of deposited platinum loadings, the rate controlling step on electro-oxidation reaction of methanol was changed from CO oxidation to sorption-desorption of hydrogen.关键词
甲醇氧化/电化学催化/聚吡咯/循环伏安/电沉积Key words
methanol electro-oxidation/ electrocatalysis/ polypyrrole/ cyclic voltammetry/ electrodepositon分类
化学化工引用本文复制引用
张玲,郑龙珍..多层聚吡咯-铂复合膜电极的甲醇电催化氧化[J].电化学,2011,17(1):84-87,4.基金项目
国家自然科学基金面上项目(20965003)、辽宁省教育厅科学技术基金(2009B169)、辽宁省科技厅博士科研启动基金项目(20101106)及沈阳师范大学实验中心主任基金(SY200806)资助 （20965003）
