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硝酸重沸器的腐蚀失效分析和防护对策

王博 李德超 李庆华 杨根柱 熊金平 陆正良

表面技术2011,Vol.40Issue(1):63-67,5.
表面技术2011,Vol.40Issue(1):63-67,5.

硝酸重沸器的腐蚀失效分析和防护对策

Failure Analysis and Protection of Nitric Acid Multiple-boiler

王博 1李德超 1李庆华 1杨根柱 1熊金平 2陆正良3

作者信息

  • 1. 中国石油化工股份有限公司,石家庄炼化分公司,石家庄,050032
  • 2. 北京化工大学,碳纤维及功能高分子教育部重点实验室,北京,100029
  • 3. 北京钢铁研究总院,北京,100081
  • 折叠

摘要

Abstract

The corrosion of the nitric acid multiple-boiler made of 304L SS was studied by optical microscope,SEM and other surface technique. The experimental results show that the non-sensitive intergranular corrosion takes place on the 304L SS of the nitric acid multiple-boiler at 89℃,55% nitric acid. The corrosive medium diffuses towards both the steel inner along grain boundary and both side of grain boundary. The P content in grain boundary is higher 2 order of magnitude than that in grain, which induces the potential difference between the grain and grain boundary in corrosive medium, and resultes in the corrosion on the non-sensitive steel.

关键词

重沸器/304L 不锈钢/腐蚀/失效分析

Key words

multiple-boiler/ 304L SS/ corrosion/ failure analysis

分类

矿业与冶金

引用本文复制引用

王博,李德超,李庆华,杨根柱,熊金平,陆正良..硝酸重沸器的腐蚀失效分析和防护对策[J].表面技术,2011,40(1):63-67,5.

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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